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A theoretical thermodynamic analysis of the system was carried out as a function of temperature, and the limiting current densities, kinetic parameters, including the Tafel slopes and current exchange density, and apparent activation energies were determined. The electrochemical promotion of electrocatalysis EPOE was investigated by carrying out the electrolysis in triode and tetrode operation. It was shown to improve the PEM electrolysis in the galvanostatic and potentiostatic modes. A decrease in electrolysis voltage or an increase in electrolysis current proportional to the current or potential imposed in the auxiliary circuit was observed when the auxiliary current or potential was opposite to the electrolyser circuit current or potential.
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